use Encode::Locale;
use Encode 'encode';
...;
$Conf{BackupFilesOnly} = {
  'D$' => [
    '/CHESTER/volumouse_beta',
    '/TorrentSMASHA/tmp',
    encode(locale => "/\x{43f}\x{440}\x{43e}\x{43b}\x{43e}\x{433}"),
  ]
};

WinXX
One setup for WinXX clients is to set $Conf{XferMethod} to "smb". Actually, rsyncd is the better method for WinXX if you are prepared to run rsync/cygwin on your WinXX client.

If you want to use rsyncd for WinXX clients you can find a pre-packaged zip file on http://backuppc.sourceforge.net. The package is called cygwin-rsync. It contains rsync.exe, template setup files and the minimal set of cygwin libraries for everything to run. The README file contains instructions for running rsync as a service, so it starts automatically everytime you boot your machine. If you use rsync to backup WinXX machines, be sure to set $Conf{ClientCharset} correctly (eg: 'cp1252') so that the WinXX file name encoding is correctly converted to utf8.

Otherwise, to use SMB, you can either create shares for the data you want to backup or your can use the existing C$ share. To create a new share, open "My Computer", right click on the drive (eg: C), and select "Sharing..." (or select "Properties" and select the "Sharing" tab). In this dialog box you can enable sharing, select the share name and permissions.

All Windows NT based OS (NT, 2000, XP Pro), are configured by default to share the entire C drive as C$. This is a special share used for various administration functions, one of which is to grant access to backup operators. All you need to do is create a new domain user, specifically for backup. Then add the new backup user to the built in "Backup Operators" group. You now have backup capability for any directory on any computer in the domain in one easy step. This avoids using administrator accounts and only grants permission to do exactly what you want for the given user, i.e.: backup. Also, for additional security, you may wish to deny the ability for this user to logon to computers in the default domain policy.